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NAKATA　Norio
Material Science DivisionProfessor
Chemistry

Researcher information

■ Degree
  • 博士（理学）, Kyoto University
    Mar. 2003
■ Field Of Study
  • Nanotechnology/Materials, Polymer chemistry
  • Nanotechnology/Materials, Inorganic and coordination chemistry
  • Nanotechnology/Materials, Synthetic organic chemistry, main group element chemistry
  • Nanotechnology/Materials, Structural/physical organic chemistry
■ Career
  • Apr. 2024 - Present, Rikkyo University, College of Science Department of Chemistry
  • Apr. 2024 - Present, Saitama University, Graduate School of Science and Engineering, Professor
  • Apr. 2022 - Mar. 2024, Saitama University, Graduate School of Science and Engineering
  • Jun. 2017 - Mar. 2024, Rikkyo University, College of Science Department of Chemistry, Japan
  • Apr. 2007 - Mar. 2022, Saitama University, Graduate School of Science and Engineering, Japan
  • Jun. 2014 - Mar. 2017, RIKEN, Center for Emergent Matter Science, Japan
  • Sep. 2011 - Feb. 2013, Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée, France
  • Apr. 2006 - Mar. 2007, Saitama University, Graduate School of Science and Engineering, Japan
  • Apr. 2004 - Mar. 2006, University of Tsukuba, Japan
  • Jan. 2004 - Mar. 2004, University of Tsukuba, Japan
  • Apr. 2003 - Dec. 2003, University of Tsukuba, Japan
■ Educational Background
  • Apr. 2000 - Mar. 2003, Kyoto University, Japan
  • Apr. 1998 - Mar. 2000, Gifu University, Japan
■ Award
  • Jun. 2021, 第61回学術奨励賞
  • Sep. 2018, International Association of Advanced Materials, Scientist Medal
  • Dec. 2016, 日本化学会欧文誌BCSJ賞
  • Feb. 2014, 2013年度研究企画賞（三洋化成工業研究企画賞）
  • Aug. 2010, 第10回セレンテルル化学に関する国際会議・Poster Award
  • Jul. 2010, 第24回有機金属化学に関する国際会議・Best Poster Award
  • Feb. 2010, 2009年度研究企画賞（塩野義製薬研究企画賞）
  • Feb. 2007, 2007年度研究企画賞（ADEKA研究企画賞）
  • Feb. 2005, 第19回若い世代の特別講演会証
  • Nov. 2001, 第6回ケイ素化学協会シンポジウムポスター賞

Performance information

■ Paper
■ MISC
  • Synthesis and photophysical property of 1-chalcogeno-1,3-butadiene derivatives and the related compounds incorporated in a dibenzobarrelene skeleton　　　　　　　　　　　　　　　
    Akihiko Ishii; Norio Nakata
    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, Volume：76, Number：10, First page：1042, Last page：1054, 2018
    Book review
    DOI：https://doi.org/10.5059/yukigoseikyokaishi.76.1042
    Scopus：https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85055051317&origin=inward
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85055051317&origin=inward
    DOI ID：10.5059/yukigoseikyokaishi.76.1042, ISSN：0037-9980, SCOPUS ID：85055051317
  • Macromol. Rapid Commun. 12/2016　　　　　　　　　　　　　　　
    Yusuke Saito; Norio Nakata; Akihiko Ishii
    Macromolecular Rapid Communications, Volume：37, Number：12, First page：1008, 01 Jun. 2016
    Report scientific journal
    DOI：https://doi.org/10.1002/marc.201670051
    Scopus：https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84975109792&origin=inward
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=84975109792&origin=inward
    DOI ID：10.1002/marc.201670051, ISSN：1022-1336, eISSN：1521-3927, SCOPUS ID：84975109792
  • Isospecific Polymerization of α-Olefins Catalyzed by Transition-metal Catalysts Supported by Cycloalkane-fused[OSSO]-type Tetradentate Ligand　　　　　　　　　　　　　　　
    石井 昭彦; 中田 憲男
    Volume：58, Number：1, First page：2, Last page：7, Jan. 2016
    Japanese
    ISSN：0559-8958, CiNii Articles ID：40020732352, CiNii Books ID：AN00117719
  • Recent advances in the chemistry of Group 4 metal complexes incorporating [OSSO]-type bis(phenolato) ligands as post-metallocene catalysts　　　　　　　　　　　　　　　
    Norio Nakata; Tomoyuki Toda; Akihiko Ishii
    Polymer Chemistry, Volume：2, Number：8, First page：1597, Last page：1610, Aug. 2011
    Book review
    DOI：https://doi.org/10.1039/c1py00058f
    Scopus：https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=79960303151&origin=inward
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=79960303151&origin=inward
    DOI ID：10.1039/c1py00058f, ISSN：1759-9954, eISSN：1759-9962, SCOPUS ID：79960303151
  • Study on the effective and selective synthetic reaction with transition metal　　　　　　　　　　　　　　　
    石井 昭彦; 中田 憲男; 芦田 彪; 加藤 淳一; 新井 輝明; 森 さやか
    Number：2, First page：23, Last page：25, 2009
    The thermal reaction of a (dibenzobarreleneselenolato)(hydrido)platinum(II) complex gave twofour-membered selenaplatinacycles, one of which is formed by hydroplatination of the Pt-H bond to the etheno bridge and the other is a vinylic C-H bond activation. The reaction mechanism for the cyclometalation is investigated.
    Japanese
    ISSN：1883-8278, CiNii Articles ID：120002354108, CiNii Books ID：AA12486867
  • Study on the effective and selective synthetic reaction with transition metal catalysts
    石井 昭彦; 中田 憲男; 芦田 彪; 加藤 淳一; 新井 輝明; 森 さやか
    Report of Comprehensive Open Innovation Center, Saitama University, Number：1, First page：30, Last page：32, 2008
    The oxidative addition of [Pt(2-nb)(PPh3)2] with a sterically hindered thiol TripSH (Trip = 9-triptycyl) in toluene afforded cis-hydrido(thiolato) Pt(II) complex PtH(Strip)(PPh3)2 as thermally and moisture stable colorless crystals in 91% yield. The thermal reaction of PtH(Strip)(PPh3)2 gave the corresponding thiaplatinacycle. The first stable dihydrogermyl(hydrido) platinum(II) complex PtH(GeH2Trip)(Ph3P)2 was synthesized by the oxidative addition reaction of TripGeH3 with Pt( 2-C2H4)(Ph3P)2 in toluene. The reaction of TripGeH3 with (dppe)PtCl2 in the presence of NaBH4 afforded the corresponding hydrido complex PtH(GeH2Trip)(dppe) together with bis(germyl) platinum(II) complex Pt(GeH2Trip)2(dppe). The ligand exchange reaction of PtH(GeH2Trip)(Ph3P)2 with Cy2PCH2CH2PCy2 (DCPE) in toluene resulted in the formation of PtH(GeH2Trip)(dcpe) in the moderate yield. Thermal rearrangement of Pt(GeH2Trip)2(dppe) in toluene at 60 ˚C gave digermyl(hydrido) complex PtH[Ge(Htrip)GeH2Trip](dppe) in high yield.
    Japanese
    ISSN：1883-8278, CiNii Articles ID：120001493933
■ Affiliated academic society
  • May 2017 - Present
  • Oct. 2013 - Present
  • Feb. 2012 - Present
  • Jun. 2008 - Present
  • Dec. 2004 - Present
  • Sep. 2000 - Present
  • Oct. 1997 - Present
■ Research projects
  • Coordination chemistry of stronger sigma-donating N-heterocyclic silylenes than carbenes　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), 01 Apr. 2022 - 31 Mar. 2025
    Saitama University
    Grant amount(Total)：4290000, Direct funding：3300000, Indirect funding：990000
    Grant number：22K05138
  • Development of precise synthetic method for paraffinic fuel precursors by post-metallocene catalysts　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), 01 Apr. 2017 - 31 Mar. 2020
    Nakata Norio, Saitama University
    Grant amount(Total)：4810000, Direct funding：3700000, Indirect funding：1110000
    In this research project, we aimed to develop a precise synthetic methodology for the vinylidene dimer of 1-hexene, which can be used as precursors of alternative jet fuels. Upon activation of arious aryl-substituted [OSSO]-type zirconium complexes with 100-300 equivalents of dried modified-methylaluminoxane as a co-catalyst, the oligomerization of 1-hexene were perfectly proceeded to give the corresponding vinylidene-selective dimer as a main product. The TOF values of these reactions were found to be quite higher than those of conventional metallocene catalysts.
    Grant number：17K05771
  • ヒドリドシリレンを感応性化学種とする触媒機能の設計・開発　　　　　　　　　　　　　　　
    01 Apr. 2015 - 31 Mar. 2017
    Grant amount(Total)：5200000, Direct funding：4000000, Indirect funding：1200000
    Grant number：15H00919
  • Development and design of [OSSO]-type catalysts for precise polymerization of versatile alfa-olefins　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), 01 Apr. 2013 - 31 Mar. 2016
    Nakata Norio, Saitama University
    Grant amount(Total)：5330000, Direct funding：4100000, Indirect funding：1230000
    In order to realize precise polymerization of versatile alfa-olefins such as propylene and styrene, novel [OSSO]-type bis(phenolate) ligands based on a trans-1,2-cyclooctanediyl platform and their zircoium complexes were developed. As a result, upon activation with dMAO (dried methylaluminoxane), the complex 4 was found to promote highly isospecific styrene polymerizations ([mm] = 97.5-99%) with high molecular weights up to 181,000 g mmol-1. When the Dmp-substituted pre-catalyst 5/dMAO system was used, the highest activity over 7,700 g mmol(5)-1 h-1 was recorded involving the formation of precisely isospecific polystyrenes of [mm] more than 99%.
    Grant number：25410035
  • 生体内の硫化水素を可視化するON-OFF型蛍光プローブの開発　　　　　　　　　　　　　　　
    2014 - 2015
  • 炭素－硫黄結合ならびに酸素－水素結合の同時活性化を鍵とする新規分子変換反応の開発　　　　　　　　　　　　　　　
    01 Apr. 2011 - 31 Mar. 2013
    Grant amount(Total)：7020000, Direct funding：5400000, Indirect funding：1620000
    Grant number：23105508
  • Development of ultimate post-metallocene catalyst realizing high activity, high stereoselectivity, and living polymerization　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Young Scientists (B), Grant-in-Aid for Young Scientists (B), 2011 - 2012
    NAKATA Norio, Saitama University
    Grant amount(Total)：4680000, Direct funding：3600000, Indirect funding：1080000
    In order to realize high active, high stereoselective, and living polymerization of α-olefin, a series of novel [OSSO]-type ligands and their Group 4 and 5 transition metal complexes were developed. As a result, dMAO-activated zirconium(IV), hafnium(IV), titanium(III) and (IV), and tantalum(V) complexes having the [OSSO]-type ligand could be catalyzed the polymerization of1-hexene to produce perfectly isotactic polymers. In the presence of dMAO as an activator, especially, a dichloro zirconium(IV) pre-catalyst incorporating with the [OSSO]-type ligand was found to promote1-hexene polymerizations giving completely isotactic polymer with excellent activity of 17,300 g・mmol^<-1>・h<1>.
    Grant number：23750034
  • Study on the Reaction Mechanism of the Reaction of Isolable Hydrido-chalcogenolato Platinum Complexes with Alkynes　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), 2009 - 2011
    ISHII Akihiko; NAKATA Norio, Saitama University
    Grant amount(Total)：4940000, Direct funding：3800000, Indirect funding：1140000
    The hydroselenation of hydrido-selenolato Pt(II) complexes with alkynes was studied. On the basis of the results employing the complexes having a 9-triptycyl group on the selenium and triphenylphosphine or 1,2-(diphenylphosphino)ethane as the phosphorus ligand, it was revealed that the dissociation of a phosphorus ligand is essential in the initial stage. It is also discovered that the complex having triphenyl phosphite ligands reacts with phenylacetylene to yield the corresponding selenaplatinacycle and styrene.
    Grant number：21550035
  • 強発光性含カルコゲン複素環化合物の開発と発光材料への応用　　　　　　　　　　　　　　　
    2009 - 2009
    Principal investigator
  • 4族遷移金属-シリレン錯体の創製とそれを触媒とする新規重合反応の開発　　　　　　　　　　　　　　　
    2007 - 2008
    Grant amount(Total)：3600000, Direct funding：3600000
    Grant number：18750026
  • セレナメタラサイクルの創製と新合成反応への展開　　　　　　　　　　　　　　　
    2007 - 2007
    Grant amount(Total)：2500000, Direct funding：2500000
    Grant number：19027014
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