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KINOSHITA　Hidenori
Material Science DivisionAssociate Professor
Department of Applied Chemistry

Researcher information

■ Degree
  • Ph.D., Kyoto University
■ Research Keyword
  • Transition Metal Chemistry
  • Organometalic Chemistry
  • Synthetic Chemistry
  • Organic Chemistry
■ Field Of Study
  • Nanotechnology/Materials, Synthetic organic chemistry
  • Life sciences, Bioorganic chemistry
  • Nanotechnology/Materials, Structural/physical organic chemistry
■ Educational Background
  • 2005, Japan
  • 2005, Graduate School of Engineering Kyoto University, Graduate School of Engineering, Material Chemistry
  • 2002, Japan
  • 2002, Graduate School of Engineering Kyoto University, Graduate School of Engineering, Material Chemistry
  • 2000, Kyoto University, Faculty of Engineering, School of Industrial Chemistry, Japan
  • 2000, Kyoto University, Faculty of Engineering, Industrial Chemistry

Performance information

■ Paper
  • Regio- and Stereoselective anti-Hydroalumination of Internal and Terminal Alkynes Using a Mixed Reagent of Cesium Fluoride with Diisobutylaluminum Hydride
    Ryosuke Sakamoto; Hidenori Kinoshita; Katsukiyo Miura
    Organic Letters, Volume：27, Number：20, First page：5241, Last page：5246, May 2025, [Reviewed], [Corresponding]
    American Chemical Society (ACS), Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.5c01452
    DOI ID：10.1021/acs.orglett.5c01452, ISSN：1523-7060, eISSN：1523-7052
  • Palladium-Catalyzed Synthesis of Silylated 3,3′-Bi(3,8-dihydrocyclopenta[a]indenyls) from Silylacetylenes　　　　　　　　　　　　　　　
    Taiga Motoyama; Hidenori Kinoshita; Katsukiyo Miura
    Organic Letters, Volume：27, Number：17, First page：4496, Last page：4500, May 2025, [Reviewed], [Corresponding]
    Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.5c01024
    DOI ID：10.1021/acs.orglett.5c01024, ORCID：182540245
  • Platinum-Catalyzed Alkenylation of Acetals with Alkenylsilanes　　　　　　　　　　　　　　　
    Toma Hattori; Juri Matsuda-Komuro; Yuji Sakurazawa; Naoto Chijiwa; Daiki Fukuda; Hidenori Kinoshita; Katsukiyo Miura
    Organic Letters, Apr. 2025, [Reviewed]
    Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.5c01096
    DOI ID：10.1021/acs.orglett.5c01096, ORCID：181557331
  • Synthesis of Dihydrobenzosiloles and Silacyclopentanes by Double Hydroalumination of Terminal Alkynes　　　　　　　　　　　　　　　
    Ryusei Osawa; Kotaro Ogihara; Fumine Hamasaki; Hidenori Kinoshita; Katsukiyo Miura
    Synlett, Volume：36, Number：3, First page：284, Last page：288, Feb. 2025, [Reviewed], [Corresponding]
    Scientific journal
    DOI：https://doi.org/10.1055/A-2330-0874
    DOI ID：10.1055/A-2330-0874, ORCID：166768983, Web of Science ID：WOS:001237508500002
  • Platinum-Catalyzed Hydrative Dimerization of Alkynylsilanes to α,β-Unsaturated Ketones　　　　　　　　　　　　　　　
    Kasumi Kikuchi-Igarashi; Yuki Tahara; Haruna Hirano; Chinatsu Ambe; Hidenori Kinoshita; Katsukiyo Miura
    Organic Letters, Jul. 2024, [Reviewed]
    Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.4c01735
    DOI ID：10.1021/acs.orglett.4c01735, ORCID：162806260
  • Synthetic Route to Benzostannoles via Al−Li‐dimetal Intermediate and Their Application to Dibenzofulvene Synthesis　　　　　　　　　　　　　　　
    Rei Kurokawa; Hidenori Kinoshita; Katsukiyo Miura
    Advanced Synthesis & Catalysis, Volume：366, First page：1523, Last page：1530, Apr. 2024, [Reviewed], [Corresponding]
    Scientific journal
    DOI：https://doi.org/10.1002/adsc.202301373
    DOI ID：10.1002/adsc.202301373, ORCID：153710604
  • Palladium-Catalyzed Synthesis of 3,6-Diaryl-1-silylfulvenes: A Promising Entry for Preparing 1,3,6-Triarylfulvenes Bearing Three Different Aryl Groups　　　　　　　　　　　　　　　
    Hayato Ohki; Hidenori Kinoshita; Katsukiyo Miura
    Organic Letters, Volume：25, Number：8, First page：1331, Last page：1335, Mar. 2023, [Reviewed], [Corresponding]
    Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.3c00340
    DOI ID：10.1021/acs.orglett.3c00340, ORCID：129352471
  • One-Pot Direct Synthesis of Siloles from 1-Bromo-2-silylethynylbenzenes or 1-Bromo-4-silyl-1,3-enynes　　　　　　　　　　　　　　　
    Koyo Kazama; Rei Kurokawa; Kei Inoue; Hidenori Kinoshita; Katsukiyo Miura
    The Journal of Organic Chemistry, Volume：87, Number：15, First page：10416, Last page：10421, Aug. 2022, [Reviewed], [Corresponding]
    English, Scientific journal
    DOI：https://doi.org/10.1021/acs.joc.2c00847
    DOI ID：10.1021/acs.joc.2c00847, ISSN：0022-3263, eISSN：1520-6904, ORCID：115586401, Web of Science ID：WOS:000826704700001
  • Regio- and stereoselective synthesis of bromoalkenes by homolytic hydrobromination of alkynes with hydrogen bromide　　　　　　　　　　　　　　　
    Wataru Kumaki; Hidenori Kinoshita; Katsukiyo Miura
    Tetrahedron, Volume：110, First page：132687, Last page：132687, Feb. 2022, [Reviewed]
    Elsevier {BV}, English, Scientific journal
    DOI：https://doi.org/10.1016/j.tet.2022.132687
    Scopus：https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85125436506&origin=inward
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85125436506&origin=inward
    DOI ID：10.1016/j.tet.2022.132687, ISSN：0040-4020, eISSN：1464-5416, ORCID：109219580, SCOPUS ID：85125436506
  • Electrochemical Properties and Electrochromism of 6-Aryl-1,3-bis(trimethylsilyl)fulvenes and Their Derivatives　　　　　　　　　　　　　　　
    Tatemura, R.; Yasutake, M.; Kinoshita, H.; Miura, K.
    Journal of Organic Chemistry, Volume：87, Number：1, First page：172, Last page：183, 2022, [Reviewed], [Corresponding]
    English, Scientific journal
    DOI：https://doi.org/10.1021/acs.joc.1c02133
    DOI ID：10.1021/acs.joc.1c02133, ISSN：1520-6904, eISSN：1520-6904, ORCID：109005293, SCOPUS ID：85121901069, Web of Science ID：WOS:000759551400016
  • Synthesis of Polysubstituted Germoles and Benzogermoles Using a Substoichiometric Amount of Diisobutylaluminum Hydride　　　　　　　　　　　　　　　
    Kojima, K.; Uchida, S.; Kinoshita, H.; Miura, K.
    Organic Letters, Volume：23, Number：12, First page：4598, Last page：4602, 2021, [Reviewed], [Corresponding]
    English, Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.1c01314
    DOI ID：10.1021/acs.orglett.1c01314, ISSN：1523-7052, eISSN：1523-7052, ORCID：109005302, SCOPUS ID：85108438077, Web of Science ID：WOS:000664333200019
  • Cyclization of 1-ethynyl-2-alkenylbenzenes to naphthalenes using Et2AlCl and DIBAL-H　　　　　　　　　　　　　　　
    Yuma Nonoyama; Kazuki Yaguchi; Hidenori Kinoshita; Katsukiyo Miura
    Tetrahedron Letters, Volume：62, First page：152682, Last page：152682, Jan. 2021, [Reviewed], [Corresponding]
    Elsevier {BV}, Scientific journal
    DOI：https://doi.org/10.1016/j.tetlet.2020.152682
    Scopus：https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85097782886&origin=inward
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85097782886&origin=inward
    DOI ID：10.1016/j.tetlet.2020.152682, ISSN：0040-4039, eISSN：1873-3581, ORCID：84686216, SCOPUS ID：85097782886
  • Diisobutylaluminum Hydride Promoted Selectivity-Switchable Synthesis of Benzothiophene Oxides and Benzothiophenes via an Al–Li-Dimetalated Intermediate　　　　　　　　　　　　　　　
    Seiya Uchida; Hidenori Kinoshita; Katsukiyo Miura
    Organic Letters, Volume：22, Number：8, First page：3123, Last page：3127, Apr. 2020, [Reviewed], [Corresponding]
    English, Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.0c00884
    DOI ID：10.1021/acs.orglett.0c00884, ISSN：1523-7052, eISSN：1523-7052, ORCID：71448383, SCOPUS ID：85082799009, Web of Science ID：WOS:000526894000052
  • Indium(III)-catalyzed intramolecular addition of silyl enolates to alkynes
    Hidenori Kinoshita; Kenta Negishi; Saya Fushimi; Katsukiyo Miura
    Tetrahedron Letters, Volume：60, Number：26, First page：1732, Last page：1735, Jun. 2019, [Reviewed], [Lead]
    Elsevier {BV}, Scientific journal
    DOI：https://doi.org/10.1016/j.tetlet.2019.05.055
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85066404597&origin=inward
    DOI ID：10.1016/j.tetlet.2019.05.055, ISSN：1873-3581, eISSN：1873-3581, ORCID：57912117, SCOPUS ID：85066404597
  • Palladium-Catalyzed Regio- and Stereoselective Synthesis of (E)-1,3-Bissilyl-6-arylfulvenes from Aryl Iodides and Silylacetylenes　　　　　　　　　　　　　　　
    Souta Suzuki; Hidenori Kinoshita; Katsukiyo Miura
    Organic Letters, Volume：21, Number：6, First page：1612, Last page：1616, Mar. 2019, [Reviewed], [Corresponding]
    English, Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.9b00144
    DOI ID：10.1021/acs.orglett.9b00144, ISSN：1523-7052, eISSN：1523-7052, ORCID：54426895, SCOPUS ID：85062369069, Web of Science ID：WOS:000461843900013
  • Development of intramolecular C-C and C-Si bond forming reactions promoted by diisobutylaluminum hydride
    Kinoshita, H.; Miura, K.
    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, Volume：77, Number：1, First page：62, Last page：72, 2019, [Lead, Corresponding]
    Scientific journal
    DOI：https://doi.org/10.5059/yukigoseikyokaishi.77.58
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85060898262&origin=inward
    DOI ID：10.5059/yukigoseikyokaishi.77.58, ISSN：0037-9980, ORCID：109005296, SCOPUS ID：85060898262
  • Syntheses of substituted benzosiloles and siloles by diisobutylaluminium hydride-promoted cyclization of 1-silyl-2-(2-silylethynyl)benzenes and 1,4-disilylalk-3-en-1-ynes
    Hidenori Kinoshita; Hiroki Fukumoto; Akihiro Ueda; Katsukiyo Miura
    Tetrahedron, Volume：74, Number：14, First page：1632, Last page：1645, Feb. 2018, [Reviewed], [Corresponding]
    Elsevier {BV}, Scientific journal
    DOI：https://doi.org/10.1016/j.tet.2018.02.011
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85041948541&origin=inward
    DOI ID：10.1016/j.tet.2018.02.011, ISSN：0040-4020, eISSN：1464-5416, ORCID：41970399, SCOPUS ID：85041948541
  • Diisobutylaluminum hydride-promoted cyclization of silylated 1,3-dien-5-ynes: Application to total synthesis of a 20-norabietane derivative　　　　　　　　　　　　　　　
    Hidenori Kinoshita; Kazuki Yaguchi; Takayuki Tohjima; Katsukiyo Miura
    Tetrahedron Letters, Mar. 2017, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1016/j.tetlet.2017.03.022
    DOI ID：10.1016/j.tetlet.2017.03.022, ORCID：31119578
  • Diisobutylaluminum Hydride Promoted Cyclization of 1-Hydrosilyl-4-silyl-1,3-enynes to Polysubstituted Siloles　　　　　　　　　　　　　　　
    Hidenori Kinoshita; Akihiro Ueda; Hiroki Fukumoto; Katsukiyo Miura
    Organic Letters, Volume：19, Number：4, First page：882, Last page：885, Feb. 2017, [Reviewed], [Lead], ［International magazine］
    An efficient method for preparing unsymmetrically multisubstituted siloles is described. The reaction of 1-hydrosilyl-4-silyl-1,3-enynes with diisobutylaluminum hydride (DIBAL-H) gave multisubstituted siloles in good to high yields. This method could be applied to the synthesis of benzosiloles using 2-hydrosilyl-1-(silylethynyl)benzenes as substrates. The silole formation was also promoted even by a substoichiometric amount of DIBAL-H. The reaction provides a straightforward method to prepare siloles and benzosiloles.
    English, Scientific journal
    DOI：https://doi.org/10.1021/acs.orglett.7b00038
    DOI ID：10.1021/acs.orglett.7b00038, ORCID：29989206, PubMed ID：28145717
  • Cyclization of alk-5-ynyl ketones promoted by Tf2NH and In(OTf)3: selective synthesis of 5- and 7-membered carbocycles　　　　　　　　　　　　　　　
    Hidenori Kinoshita; Chika Miyama; Katsukiyo Miura
    Tetrahedron Letters, Volume：57, Number：46, First page：5065, Last page：5069, Nov. 2016, [Reviewed], [Lead]
    Elsevier {BV}, Scientific journal
    DOI：https://doi.org/10.1016/j.tetlet.2016.10.003
    DOI ID：10.1016/j.tetlet.2016.10.003, ORCID：28011420
  • Diisobutylaluminum hydride-promoted cyclization of benzyl and phenylsilyl ethers bearing a 2-(trimethylsilyl)ethynyl group: syntheses of indenes and benzosiloles　　　　　　　　　　　　　　　
    Hidenori Kinoshita; Hiroki Fukumoto; Takayuki Tohjima; Katsukiyo Miura
    Tetrahedron Letters, Volume：57, Number：31, First page：3571, Last page：3574, Aug. 2016, [Reviewed], [Lead]
    Elsevier {BV}, Scientific journal
    DOI：https://doi.org/10.1016/j.tetlet.2016.06.123
    DOI ID：10.1016/j.tetlet.2016.06.123, ORCID：25025848
  • Regioselective Allylation of Carbon Electrophiles with Alkenylsilanes under Dual Catalysis by Cationic Platinum(II) Species　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Kizu, Ryosuke; Horikoshi, Masahiro; Inoue, Gen; Fujimoto, Masayuki; Saito, Masanori; Ichikawa, Junji; Hosomi, Akira; Miura, Katsukiyo
    Synthesis-Stuttgart, Volume：48, Number：4, 2016, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1055/s-0035-1560380
    DOI ID：10.1055/s-0035-1560380, ISSN：1437-210X, ORCID：22757622, SCOPUS ID：84957434861, Web of Science ID：WOS:000369749600005
  • Diisobutylaluminum hydride-promoted cyclization of o-(trimethylsilylethynyl)styrenes to substituted naphthalenes　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Yaguchi, Kazuki; Tohjima, Takayuki; Hirai, Nobuyoshi; Miura, Katsukiyo
    Tetrahedron Letters, Volume：57, Number：19, 2016, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1016/j.tetlet.2016.03.099
    DOI ID：10.1016/j.tetlet.2016.03.099, ORCID：24401224, Web of Science ID：WOS:000375338700006
  • Platinum-catalyzed allylation of carbon electrophiles with alkenylsilanes　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Kizu, Ryosuke; Inoue, Gen; Fujimoto, Masayuki; Saito, Masanori; Ichikawa, Junji; Hosomi, Akira; Miura, Katsukiyo
    Tetrahedron Letters, Volume：56, Number：5, 2015, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1016/j.tetlet.2014.12.077
    DOI ID：10.1016/j.tetlet.2014.12.077, ORCID：20026986, Web of Science ID：WOS:000348265000014
  • Hydroalumination-Triggered Cyclization of Silylated 1,3-Dien-5-ynes to Polysubstituted Benzenes　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Tohjima, Takayuki; Miura, Katsukiyo
    Organic Letters, Volume：16, Number：18, First page：4762, Last page：5, 2014, [Reviewed], [Lead], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol5022096
    DOI ID：10.1021/ol5022096, ORCID：20026988, PubMed ID：25188533, Web of Science ID：WOS:000342117600018
  • Diisobutylaluminum Hydride Promoted Cyclization of o-(Trimethylsilylethynyl)styrenes to Indenes　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Hirai, Nobuyoshi; Miura, Katsukiyo
    Journal of Organic Chemistry, Volume：79, Number：17, First page：8171, Last page：81, 2014, [Reviewed], [Lead], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/jo501383v
    DOI ID：10.1021/jo501383v, ORCID：20026987, PubMed ID：25093271, Web of Science ID：WOS:000341345400040
  • Synthetic utility of tribenzyltin hydride and its derivatives as easily accessible, removable, and decomposable organotin reagents　　　　　　　　　　　　　　　
    Yamakawa, Takeshi; Kinoshita, Hidenori; Miura, Katsukiyo
    Journal of Organometallic Chemistry, Volume：724, 2013, [Reviewed]
    Scientific journal
    DOI：https://doi.org/10.1016/j.jorganchem.2012.11.007
    DOI ID：10.1016/j.jorganchem.2012.11.007, ORCID：20026992, Web of Science ID：WOS:000314113400017
  • Regioselective Synthesis of Multisubstituted Benzenes by Palladium-Catalyzed Intermolecular Reaction of beta-lodo/beta-silylstyrenes with Alkynes　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Takahashi, Hirotoshi; Miura, Katsukiyo
    Organic Letters, Volume：15, Number：12, First page：2962, Last page：5, 2013, [Reviewed], [Lead], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol4010883
    DOI ID：10.1021/ol4010883, ORCID：20026991, PubMed ID：23731377, Web of Science ID：WOS:000320979000019
  • Platinum-Catalyzed One-Pot Alkenylation of Aldehydes Using Alkynes and Triethylsilane: Dual Catalysis by Platinum(II) Chloride　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Uemura, Ryousuke; Fukuda, Daiki; Miura, Katsukiyo
    Organic Letters, Volume：15, Number：21, First page：5538, Last page：5541, 2013, [Reviewed], [Lead]
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol4026952
    DOI ID：10.1021/ol4026952, ISSN：1523-7060, eISSN：1523-7052, ORCID：20026990, Web of Science ID：WOS:000326615100037
  • Nucleophilic Addition of alpha-(Dimethylsilyl)nitriles to Aldehydes and Ketones　　　　　　　　　　　　　　　
    Jinzaki, Takaaki; Arakawa, Mitsuru; Kinoshita, Hidenori; Ichikawa, Junji; Miura, Katsukiyo
    Organic Letters, Volume：15, Number：14, First page：3750, Last page：3753, 2013, [Reviewed]
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol401663u
    DOI ID：10.1021/ol401663u, ISSN：1523-7060, ORCID：20026989, Web of Science ID：WOS:000322210600067
  • Dialkylaluminum Hydride-Promoted Cyclodimerization of Silylated 1,3-Enynes via Skeletal Rearrangement　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Ishikawa, Tomoyuki; Miura, Katsukiyo
    Organic Letters, Volume：13, Number：23, First page：6192, Last page：5, 2011, [Reviewed], [Lead], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol202601s
    DOI ID：10.1021/ol202601s, ORCID：20026993, PubMed ID：22043921, Web of Science ID：WOS:000297274700015
  • Tandem Processes Identified from Reaction Screening: Nucleophilic Addition to Aryl N-Phosphinylimines Employing La(III)-TFAA Activation　　　　　　　　　　　　　　　
    Kinoshita, Hidenori; Ingham, Oscar J.; Ong, Winnie W.; Beeler, Aaron B.; Porco, John A., Jr.
    Journal of the American Chemical Society, Volume：132, Number：18, First page：6412, Last page：8, 2010, [Reviewed], [Lead], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ja100346w
    DOI ID：10.1021/ja100346w, ORCID：20026995, PubMed ID：20394364, PubMed Central ID：PMC2881420, Web of Science ID：WOS:000277445400032
  • Indium(III)-catalyzed Coupling between Alkynes and Aldehydes to alpha,beta-Unsaturated Ketones　　　　　　　　　　　　　　　
    Miura, Katsukiyo; Yamamoto, Kiyomi; Yamanobe, Aya; Ito, Keisuke; Kinoshita, Hidenori; Ichikawa, Junji; Hosomi, Akira
    Chemistry Letters, Volume：39, Number：7, 2010, [Reviewed]
    Scientific journal
    DOI：https://doi.org/10.1246/cl.2010.766
    DOI ID：10.1246/cl.2010.766, ORCID：20026994, Web of Science ID：WOS:000280243900044
  • Platinum-Catalyzed Nucleophilic Addition of Vinylsilanes at the beta-Position　　　　　　　　　　　　　　　
    Miura, Katsukiyo; Inoue, Gen; Sasagawa, Hisashi; Kinoshita, Hidenori; Ichikawa, Junji; Hosomi, Akira
    Organic Letters, Volume：11, Number：21, First page：5066, Last page：5069, 2009, [Reviewed]
    Scientific journal
    DOI：https://doi.org/10.1021/ol902060r
    Scopus：https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=70350635768&origin=inward
    Scopus Citedby：https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=70350635768&origin=inward
    DOI ID：10.1021/ol902060r, ISSN：1523-7060, ORCID：20026997, SCOPUS ID：70350635768, Web of Science ID：WOS:000271097100076
  • Platinum(II)-catalyzed Acetal-Ene Reaction: Easy Access to Homoallylic Ethers　　　　　　　　　　　　　　　
    Miura, Katsukiyo; Izumi, Hiroyuki; Kinoshita, Hidenori; Ichikawa, Junji; Hosomi, Akira
    Chemistry Letters, Volume：38, Number：12, 2009, [Reviewed]
    Scientific journal
    DOI：https://doi.org/10.1246/cl.2009.1204
    DOI ID：10.1246/cl.2009.1204, ORCID：20026996, Web of Science ID：WOS:000273859200039
  • Synthesis of medium- and large-sized lactones in an aqueous-organic biphasic system　　　　　　　　　　　　　　　
    Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Angewandte Chemie-International Edition, Volume：44, Number：16, 2005, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1002/anie.200462677
    DOI ID：10.1002/anie.200462677, ORCID：20026999, Web of Science ID：WOS:000228709200020
  • 1,2-Migration of phosphorus-centered anions on ate-type copper carbenoids and its application for the synthesis of new potent phosphine ligands　　　　　　　　　　　　　　　
    Kondo, J; Someya, H; Kinoshita, H; Shinokubo, H; Yorimitsu, H; Oshima, K
    Organic Letters, Volume：7, Number：25, First page：5713, Last page：5, 2005, [Reviewed], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol052520a
    DOI ID：10.1021/ol052520a, ISSN：1523-7060, ORCID：20026998, PubMed ID：16321029, Web of Science ID：WOS:000233778300043
  • Phosphane-free rhodium catalyst in an anionic micellar system for [4+2] annulation of dienynes　　　　　　　　　　　　　　　
    Motoda, D.; Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Angewandte Chemie - International Edition, Volume：43, Number：14, First page：1860, Last page：2, 2004, [Reviewed], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1002/anie.200353123
    DOI ID：10.1002/anie.200353123, ISSN：1433-7851, ORCID：109005318, PubMed ID：15054796, SCOPUS ID：3142699863
  • Water enables direct use of allyl alcohol for Tsuji-Trost reaction without activators　　　　　　　　　　　　　　　
    Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Organic Letters, Volume：6, Number：22, 2004, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1021/ol048207a
    DOI ID：10.1021/ol048207a, ORCID：20027002, Web of Science ID：WOS:000224691900052
  • Hydrosilylation of alkynes with a cationic rhodium species formed in an anionic micellar system　　　　　　　　　　　　　　　
    Sato, A; Kinoshita, H; Shinokubo, H; Oshima, K
    Organic Letters, Volume：6, Number：13, First page：2217, Last page：20, 2004, [Reviewed], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol049308b
    DOI ID：10.1021/ol049308b, ISSN：1523-7060, ORCID：20027000, PubMed ID：15200324, Web of Science ID：WOS:000222119400035
  • Rhodium-catalyzed [2 + 2 + 2] cyclotrimerization in an aqueous-organic biphasic system　　　　　　　　　　　　　　　
    Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Journal of the American Chemical Society, Volume：125, Number：26, First page：7784, Last page：5, 2003, [Reviewed], [Lead], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ja035438o
    DOI ID：10.1021/ja035438o, ISSN：0002-7863, ORCID：109005299, PubMed ID：12822980, SCOPUS ID：0037527845
  • Pd(O)-catalyzed reaction of alkynes with trifurylgermane and CO providing acylgermanes: The example of hydrometalcarbonylation of alkynes　　　　　　　　　　　　　　　
    Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Journal of the American Chemical Society, Volume：124, Number：16, 2002, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1021/ja0257016
    DOI ID：10.1021/ja0257016, ISSN：0002-7863, ORCID：20027006, SCOPUS ID：0037165724, Web of Science ID：WOS:000175088600026
  • Biaryl Synthesis from Two Different Aryl Halides with Tri(2-furyl)germane　　　　　　　　　　　　　　　
    Nakamura, T.; Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Organic Letters, Volume：4, Number：18, First page：3165, Last page：7, 2002, [Reviewed], ［International magazine］
    English, Scientific journal
    DOI：https://doi.org/10.1021/ol026613t
    DOI ID：10.1021/ol026613t, ISSN：1523-7060, ORCID：109005316, PubMed ID：12201743, SCOPUS ID：0012074915
  • A room temperature Kharasch reaction catalyzed by Pd(0) in a heterogeneous aqueous system　　　　　　　　　　　　　　　
    Motoda, D.; Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Advanced Synthesis & Catalysis, Volume：344, Number：3-4, 2002, [Reviewed]
    Scientific journal
    DOI：https://doi.org/10.1002/1615-4169(200206)344:3/4<261::AID-ADSC261>3.0.CO;2-7
    DOI ID：10.1002/1615-4169(200206)344:3/4<261::AID-ADSC261>3.0.CO;2-7, ISSN：1615-4150, ORCID：20027004, SCOPUS ID：0346638609, Web of Science ID：WOS:000176514800004
  • Preparation of allylic germanes with tri(2-furyl)germane via π-allylpalladium species
    Kinoshita, H.; Shinokubo, H.; Oshima, K.
    Synlett, Number：11, 2002, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1055/s-2002-34872
    DOI ID：10.1055/s-2002-34872, ISSN：0936-5214, ORCID：109005301, SCOPUS ID：0036428018
  • Remarkable rate acceleration of Pd(0)-catalyzed hydrogermylation of alkynes and dienes in water　　　　　　　　　　　　　　　
    Kinoshita, H.; Nakamura, T.; Kakiya, H.; Shinokubo, H.; Matsubara, S.; Oshima, K.
    Organic Letters, Volume：3, Number：16, 2001, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1021/ol0161817
    DOI ID：10.1021/ol0161817, ISSN：1523-7060, ORCID：20027008, SCOPUS ID：0035833724, Web of Science ID：WOS:000170392300026
  • Trialkylmanganate mediated radical addition of triphenylgermane to carbon-carbon multiple bonds　　　　　　　　　　　　　　　
    Kinoshita, H.; Kakiya, H.; Oshima, K.
    Bulletin of the Chemical Society of Japan, Volume：73, Number：9, 2000, [Reviewed], [Lead]
    Scientific journal
    DOI：https://doi.org/10.1246/bcsj.73.2159
    DOI ID：10.1246/bcsj.73.2159, ORCID：20027009, Web of Science ID：WOS:000089687700028
■ MISC
  • Synthesis of functionalized amino-indanes via tandem aza-Prins and intramolecular Friedel-Crafts reactions of aryl N-phosphinylimines　　　　　　　　　　　　　　　
    Oscar J. Ingham; Hidenori Kinoshita; Aaron B. Beeler; John A. Porco
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Volume：240, Aug. 2010
    English, Summary international conference
    ISSN：0065-7727, Web of Science ID：WOS:000208164704648
■ Affiliated academic society
  • American Chemical Society
■ Research projects
  • Synthesis of multisubstituted stannoles bearing different substituents and its application to electrochromic materials　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (C), 01 Apr. 2023 - 31 Mar. 2026
    Saitama University
    Grant amount(Total)：4680000, Direct funding：3600000, Indirect funding：1080000
    Grant number：23K04748
  • 異なる置換基を有する多置換フルベンの合成とエレクトロクロミズム材料への応用　　　　　　　　　　　　　　　
    01 Apr. 2020 - 31 Mar. 2023
    Grant amount(Total)：4420000, Direct funding：3400000, Indirect funding：1020000
    Grant number：20K05505
  • Regioselective Synthesis of Polysubstituted Bneznes by Cross Reaction of Silylated 1,3-Enynes Using Diisobutylaluminum Hydride: Synthesis and Application　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Young Scientists (B), Grant-in-Aid for Young Scientists (B), 01 Apr. 2012 - 31 Mar. 2014
    KINOSHITA Hidenori, Saitama University
    Grant amount(Total)：4680000, Direct funding：3600000, Indirect funding：1080000
    Diisobutylaluminum hydride (DIBAL-H)-promoted reaction of silylated 1,3-enynes provided tetrasubstituted benzenes with complete regioselectivity. The reaction proceeds through dimerization of silylated 1,3-enynes via skeletal rearrengment. Stepwise cross-reaction between two different silylated 1,3-enynes also proceeds to give o,o-bissilylated styrenes in moderate yields. In the latter case, addition of ether enables the stepwise reaction. Silylated acetylenes could also be used instead of the 1,3-enynes. The stilbenes, which could be synthesized by the present reaction, exhibit efficient fluorescence emission in solid and crystal state. The fluorescence quantum yield of one o,o-bissilylstilbenes is 111 times larger than that of dichloromethane solution. Due to the bulky trimethylsilyl group inhibits the crystals from packing tightly to cause concentration quenching. Consequently, the crystals exhibit efficient fluorescence emission.
    Grant number：24750082
  • Development of Efficient Synthetic Reactions Using Unique Properties of Water　　　　　　　　　　　　　　　
    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Research Activity Start-up, Grant-in-Aid for Research Activity Start-up, 2009 - 2010
    KINOSHITA Hidenori, Saitama University
    Grant amount(Total)：2704000, Direct funding：2080000, Indirect funding：624000
    Water has unique properties which organic solvents do not have. The use of water for organic synthesis is not only environmentally friendly but also increases the efficiency of synthetic reactions. We therefore studied Pt(II)-catalyzed cyclization of alkynyl carbonyls in water. Particularly, our interest was focused on synthetic use of the π-Lewis acidity of Pt(II) catalysts in water. After exploring a wide range of conditions, we came to the realization that the desired cyclization did not proceed. However, during this study, we found that Pt(II)-catalyzed hydrative dimerization of alkynes to α, ss-unsaturated ketones.
    Grant number：21850005
  • 水中での疎水性反応場における加速効果の有機合成への利用　　　　　　　　　　　　　　　
    2002 - 2004
    Grant amount(Total)：3000000, Direct funding：3000000
    Grant number：02J01960
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